Stabilization of Classical [B 2 H 5 ] − : Structure and Bonding of [(Cp*Ta) 2 (B 2 H 5 )(μ‐H)L 2 ] (Cp*=η 5 ‐C 5 Me 5 ; L=SCH 2 S)

نویسندگان
چکیده

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Mass spectra of the 2 , 4 - pentadiynylidyne ( C 5 H ; X 2 ) and 2 , 4 - pentadiynyl - 1 ( n - C 5 H 3 ; X 2 B 1 ) radicals

We employed the crossed molecular beams method to synthesize the 2,4-pentadiynylidyne, C5H (X2 ), and the 2,4-pentadiynyl-1, nC5H3(XB1), radicals in situ under single collision conditions via the reactions of tricarbon molecules with acetylene and ethylene, respectively. Time-of-flight spectra of the radicals were recorded at the center-of-mass angles at various mass-to-charge ratios from m/z= ...

متن کامل

4 . 5 H 2 O , ( Him / imidazole , 5 MeImH / 5 - methylimidazole and 2 , 2 ? - bipy / 2 , 2 ? - bipyridine )

N -tert -butyliminodiacetic acid (H2TEBIDA, compound 1) has been prepared and characterised by thermogravimetric analysis, FT-IR and NMR spectra, and X-ray crystallography (final R1 /0.04). The zwitterion H2TEBIDA 9 is intra -stabilised by a hydrogen bond, and H-bonded chains of zwitterions form supramolecular 2D bilayers with tert -Bu groups towards the external faces. Compounds [Cu(TEBIDA)(H2...

متن کامل

The Synthesis and Crystal Structure of ( / ? * , / ? * ) - ( ± ) - [ ( i / 5 - C 5 H 5 ) { 1 , 2 -

Primary and secondary phosphine complexes are convenient precursors of terminal phosphido-metal compounds by deprotonation. Recent work has shown that the chiral tertiary phosphido-metal group Fe —PMePh can be generated stereospecifically by deprotonation of a resolved secondary phosphine complex at —90 °C, and, furthermore, that it can be alkylated with retention of configuration and com­ plet...

متن کامل

Three-dimensional quantitative structure activity relationship approach series of 3-Bromo-4-(1-H-3-Indolyl)-2, 5-Dihydro-1H-2, 5- Pyrroledione as antibacterial agents

The use of quantitative structure–activity relationships, since its advent, has becomeincreasingly helpful in understanding many aspects of biochemical interactions in drug research.This approach was utilized to explain the relationship of structure with biological activity ofantibacterial. For the development of new fungicides against, the quantitative structural–activityrelationship (QSAR) an...

متن کامل

Editorial Volume 5, Issue 2

Our Journal's tendency towards the real world in applied linguistics and literary studies should have significant epistemological and methodological consequences in researching the fields. The interest in the real world makes the problems we may have in our everyday lives our 'points of departure' in research. According to my experience of research in our universities throughout their history, ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Angewandte Chemie International Edition

سال: 2019

ISSN: 1433-7851,1521-3773

DOI: 10.1002/anie.201911480